01 / APPROACH発光性メソゲンを設計Design emissive mesogens
YAMADA / 04 — PLLC
発光性液晶の開発Development of Luminescent Liquid Crystals
分子の相転移を光の変化としてとらえる機能材料を探究する。Connecting phase transitions with photoluminescent responses.
関連論文を見るExplore related papers ↘
01 / OVERVIEW
研究概要Research overview
発光性液晶は、分子の集合秩序と発光特性を組み合わせた機能性材料です。当研究室では、ドナー–π–アクセプター（D–π–A）型の含フッ素トラン・ビストランを中心に、発光と液晶性を両立する分子を開発しています。
結晶・液晶・等方相への相転移に伴う発光波長や強度の変化に着目し、柔軟鎖の長さ、フッ素置換、二量体構造、末端基などが相挙動と発光特性に与える影響を調べます。温度応答型の光機能材料への展開を視野に、分子設計を進めています。
Photoluminescent liquid crystals combine molecular ordering with light emission. Our research focuses on fluorinated donor–π–acceptor (D–π–A) tolane and bistolane mesogens designed to exhibit both liquid-crystalline behavior and photoluminescence.
We investigate changes in emission wavelength and intensity associated with transitions among crystalline, liquid-crystalline, and isotropic states. The effects of flexible-chain length, fluorine substitution, dimeric architectures, and terminal groups are examined in the context of thermally responsive optical materials.
02 / APPROACH
研究アプローチResearch approach
02 / APPROACH相転移と発光を同時に測定Track phase behavior and PL
03 / APPROACH温度応答を分子設計へ還元Connect thermal response to design
03 / PUBLICATIONS
関連する研究論文Related research publications
ご指定の19報を掲載しています。掲載年の新しい順に表示し、DOIから原著に移動できます。タイトルと書誌情報は既存の研究室論文データに基づきます。19 selected publications, displayed newest first. Follow the DOI link to the original article. Bibliographic details are drawn from the laboratory publication records.
Design Strategies for Compact Photoluminescent Liquid Crystals Based on Fluorinated Tolane Frameworks
2026 · Chem. Rec. 2026, 26, e202500346
doi:10.1002/tcr.202500346 ↗Multi-State Photoluminescence of Donor–π–Acceptor Tetrafluorinated Tolane Mesogenic Dimers in Solution, Crystal, and Liquid-Crystalline Phases
2025 · Crystals 15(12), 1050
doi:10.3390/cryst15121050 ↗Design of Near-UV Photoluminescent Liquid-Crystalline Dimers: Roles of Fluorinated Aromatic Ring Position and Flexible Linker
2025 · Crystals 15(10), 840
doi:10.3390/cryst15100840 ↗Chain-Length-Dependent Phase Behavior and Photoluminescence in Imidazole-Substituted Fluorinated Tolane Liquid Crystals
2025 · ChemPlusChem 90(12), e202500438
doi:10.1002/cplu.202500438 ↗Difluorinated tolane-based photoluminescent liquid crystals with imidazolium salt-terminated flexible chains: Thermophysical and photophysical properties
2024 · J. Mol. Liq. 408, 125361
doi:10.1016/j.molliq.2024.125361 ↗Effects of fluorine atoms introduced into flexible chains or mesogenic structures on their liquid-crystalline and photoluminescence characteristics
2024 · J. Mol. Liq. 393, 123545
doi:10.1016/j.molliq.2023.123545 ↗Donor-π-Acceptor-Type Fluorinated Tolane Containing a Semifluoroalkoxy Chain as a Condensed-Phase Luminophore
2023 · Molecules 28(6), 2764
doi:10.3390/molecules28062764 ↗Development of Hydrogen-Bonded Dimer-Type Photoluminescent Liquid Crystals of Fluorinated Tolanecarboxylic Acid
2023 · Crystals 13(1), 25
doi:10.3390/cryst13010025 ↗Photophysical and thermophysical behavior of D-π-A-type fluorinated diphenylacetylenes bearing an alkoxy and an ethoxycarbonyl group at both longitudinal molecular terminals
2022 · J. Fluorine Chem., 2022, 261–262, 110032
doi:10.1016/j.jfluchem.2022.110032 ↗Development of photoluminescent liquid-crystalline dimers bearing two fluorianted tolane-based luminous mesogens
2022 · J. Mol. Liq., 2022, 363, 119844
doi:10.1016/j.molliq.2022.119884 ↗Development of thermoresponsive near-infrared photoluminescent liquid crystals using hexyloxi-terminated fluorinated tolane dimers connected with an alkylene spacer
2022 · J. Mol. Liq., 2022, 362, 119755
doi:10.1016/j.molliq.2022.119755 ↗Fluorinated tolane-baed fluorophores bearing a branched flexible unit with aggregation-induced emission enhancement characteristics
2022 · New J. Chem., 2022, 46(7), 3392–3400
doi:10.1039/D1NJ05822C ↗Effect of Fluoroalkyl-Substituent in Bistolane-Based Photoluminescent Liquid Crystals on Their Physical Behavior
2021 · Crystals, 2021, 11(4), 450
doi:10.3390/cryst11040450 ↗Synthesis and Characterization of Photoluminescence Liquid Crystals Based on Flexible Chain-Bearing Pentafluorinated Bistolanes
2020 · Crystals, 2020, 10(7), 603
doi:10.3390/cryst10070603 ↗Development of light-emitting liquid-crystalline polymers with a pentafluorinated bistolane-based luminophore
2020 · New J. Chem., 2020, 44(15), 5684–5691
doi:10.1039/D0NJ00659A ↗Luminescence Tuning of Fluorinated Bistolanes via Electronic or Aggregated-Structure Control
2019 · Appl. Sci., 2019, 9(9), 1905
doi:10.3390/app9091905 ↗2-Chloroalkoxy-Substituted Pentafluorinated Bistolanes as Novel Light-Emitting Liquid Crystals
2019 · Crystals, 2019, 9(4), 195
doi:10.3390/cryst9040195 ↗Thermoresponsive luminescence properties of polyfluorinated bistolane-type light-emitting liquid crystals
2018 · Org. Biomol. Chem., 2018, 16(31), 5609–5617
doi:10.1039/C8OB01497C ↗Fluorine-containing bistolanes as light-emitting liquid crystalline molecules
2017 · Org. Biomol. Chem., 2017, 15(28), 5949–5958
doi:10.1039/C7OB01369H ↗04 / EXPLORE MORE